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991.
The phase transitions among the high-pressure polymorphic forms of CaCO3 (cc-I, cc-II, cc-III, and cc-IIIb) are investigated by dynamic diamond anvil cell (dDAC) and in situ Raman spectroscopy. Experiments are carried out at room temperature and high pressures up to 12.8 GPa with the pressurizing rate varying from 0.006 GPa/s to 0.056 GPa/s. In situ observation shows that with the increase of pressure, calcite transforms from cc-I to cc-II at ~ 1.5 GPa and from cc-II to cc-III at ~ 2.5 GPa, and transitions are independent of the pressurizing rate. Further, as the pressure continues to increase, the cc-IIIb begins to appear and coexists with cc-III within a pressure range that is inversely proportional to the pressurizing rate. At the pressurizing rates of 0.006, 0.012, 0.021, and 0.056 GPa/s, the coexistence pressure ranges of cc-III and cc-IIIb are 2.8 GPa-9.8 GPa, 3.1 GPa-6.9 GPa, 2.7 GPa-6.0 GPa, and 2.8 GPa-4.5 GPa, respectively. The dependence of the coexistence on the pressurizing rate may result from the influence of pressurizing rate on the activation process of transition by reducing the energy barrier. The higher the pressurizing rate, the lower the energy barrier is, and the easier it is to pull the system out of the coexistence state. The results of this in situ study provide new insights into the understanding of the phase transition of calcite. 相似文献
992.
In this paper, a high-performance silver-doped titanium dioxide (Ag/TiO2) humidity sensor was synthesized using a hydrothermal synthesis method for respiratory monitoring. The sensing mechanism was studied by the first principles of density functional theory (DFT). Calculations show that the doping of Ag+ ions increases the adsorption energy of TiO2 to water molecules. Furthermore, the Ti–O bond in TiO2 is broken due to the doping of Ag+ ions, which promotes the generation of Ti3+ defects. Experiments show that the doping of Ag+ ions can increase the hydroxide groups, Ti3+ defects and oxygen vacancies on the surface of TiO2, thus effectively improving the responsivity, linearity and hysteresis of the TiO2 humidity sensor. Compared to TiO2, the resistance of the Ag/TiO2 (0.5 mM) humidity sensor reaches 4.5 orders of magnitude with a high response of 39707.1, maximum hysteresis rate of 4.6%, response/recovery time of 31 s/15 s and the best linearity in a range of 11%–95% RH. In addition, the Ag/TiO2 humidity sensor has been successfully used to detect different modes of respiration and determine the respiratory rate under different respiratory states. Significantly, this work demonstrates potential application value in human healthcare and activities monitoring. 相似文献
993.
In this research paper, we propose a two-hop integrated radio frequency–visible light communication (RF–VLC) system which may provide a better option to transceive between the hospitals and some laboratory to transfer patient’s information. In the proposed system model, the data (such as patient’s lab test reports) is transmitted towards the amplify and forward (AF) relay mounted on the top of the hospital building via the RF channel. Further, the AF relay amplifies and converts the received information into corresponding optical signal using light emitting diodes (LED) and supporting circuitry. This optical signal is then forwarded towards the destination device (equipped with VLC transceiver), via the VLC channel. To analyse the performance of the system, we first derive the closed form analytical expressions for the cumulative distribution function (CDF) of the end-to-end (e2e) signal to noise ratio (SNR) of the system by using the moment generating function (MGF) of the SNR of the individual RF and VLC channels. Further, we use these statistical expressions to obtain the outage probability, average bit error rate (BER) and the average capacity of the system. Moreover, the asymptotic performance of the proposed system is also analysed to study the system’s behaviour at high SNR regimes. Finally, we studied the impact of the variations in channel parameters on the proposed system model performance through numerically simulated plots. 相似文献
994.
本文首先对某飞机原机翼外形进行了详尽的气动分析计算,然后确定了设计思路和方案,探讨了后掠角变化对机翼气动性能的影响,研究选定了减小外翼后掠角的机翼新平面形状,采用先进的CFD软件优化机翼的气动设计,根据不同设计思想进行了多个机翼的外形优化,包括新的翼剖面和弯扭配置,最后将优化设计结果与原机翼进行了对比,对比结果表明,以Q5-M2T和Q5-N2T为代表的优化结果取得了十分理想的改进效果,优化机翼提高了气动性能,机翼升阻比提高了20%-30%,满足了飞机载弹量增大后性能仍可以全面提高的设计要求。 相似文献
995.
996.
997.
H. Hu 《Journal of Optimization Theory and Applications》2005,126(2):287-308
In this paper, we study geometric condition measures and smoothness condition measures of closed convex sets, bounded linear regularity, and linear regularity. We show that, under certain conditions, the constant for the linear regularity of infinitely many closed convex sets can be characterized by the geometric condition measure of the intersection or by the smoothness condition measure of the intersection. We study also the bounded linear regularity and present some interesting properties of the general linear regularity problem.The author is grateful to the referees for valuable and constructive suggestions. In particular, she thanks a referee for drawing her attention to Corollary 5.14 of Ref. 3, which inspired her to derive Theorem 4.2 and Corollary 4.2 in the revision of this paper. 相似文献
998.
徐应祥 《宁波大学学报(理工版)》2007,20(2):206-210
应用三次紧支撑样条小波插值函数得到了求一类常微分方程组数值解的隐式公式,并求得到其局部截断误差为O(-h5).在此基础上给出1个显式校正求解公式,并讨论得到其局部截断误差为O(-h4). 相似文献
999.
SiCp/Y112铝基复合材料制备工艺及性能 总被引:2,自引:0,他引:2
3种不同铸造工艺条件下铝基复合材料的微观组织,并对其硬度进行了测定.研究表明:与全液态铸造法和半固态铸造法相比,搅熔铸造制备的SiCp/Y112铝基复合材料,其增强相SiC颗粒分布均匀,气孔率较少.是一种较理想的金属基复合材料制备工艺.未增强的Y112基体铝合金的维氏硬度高于其半固态坯料的维氏硬度;而SiCp/Y112铝基复合材料的维氏硬度明显高于基体的维氏硬度,并随着SiC颗粒的体积分数的增加其复合材料的维氏硬度不断提高. 相似文献
1000.
Yi-rang Yuan 《应用数学学报(英文版)》2007,23(2):255-268
For a coupled system of multiplayer dynamics of fluids in porous media,the characteristic finiteelement domain decomposition procedures applicable to parallel arithmetic are put forward.Techniques suchas calculus of variations,domain decomposition,characteristic method,negative norm estimate,energy methodand the theory of prior estimates are adopted.Optimal order estimates in L~2 norm are derived for the error inthe approximate solution. 相似文献